Essential oils are highly concentrated volatile aroma compounds from plants. They are usually obtained from plant by steam distillation. They usually posses the aroma of the plant/part distilled. So that is the technical stuff. Some essential oils are very beneficial for skin, while some are dermal irritants. And most essential oils are used at a dilution of 1-5% .Some Essential oils that are affordable and good for skin are palmarosa, lavender, patchouli, petitgrain, rosewood.
Other expensive oils that are good are rose, neroli, sandalwood, geranium, frankinsence.
Lists are never ending for aromatherapy-skincare.
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